Safety data sheet
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Trade name: LBV23 - Ref: GL007
1.2 Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
Application of the substance / the mixture Adhesives
1.3 Details of the supplier of the safety data sheet
Manufacturer/ Supplier
LBV Professional
704 Borough Road,
Prenton,
Wirral,
Merseyside
CH42 9JE
sales@lbvprofessional.co.uk
Further information obtainable from: 0800 9159007
1.4 Emergency telephone number:
LBV 0800 9159007SECTION
2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2 H319 Causes serious eye irritation.
STOT SE 3 H335 May cause respiratory irritation.
2.2 Label elements
Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
Hazard pictograms
GHS07
Signal word Warning
Hazard-determining components of labelling:
ethyl 2-cyanoacrylate
Hazard statements
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
Precautionary statements
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P321 Specific treatment (see on this label).
P362 Take off contaminated clothing and wash before reuse.
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P312 Call a POISON CENTER/doctor if you feel unwell.
P332+P313 If skin irritation occurs: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/attention.
P403+P235 Store in a well-ventilated place. Keep cool.
P402+P404 Store in a dry place. Store in a closed container.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Additional information:
Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Keep out of the reach of children.
2.3 Other hazards
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
SECTION 3: Composition/information on ingredients
3.2 Chemical characterisation: Mixtures
Description: Mixture of substances listed below with nonhazardous additions.
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Dangerous components: |
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|
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CAS: 7085-85-0 EINECS: 230-391-5 |
ethyl 2-cyanoacrylate
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50-100% |
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CAS: 123-31-9 EINECS: 204-617-8 |
1,4-dihydroxybenzene
Acute Tox. 4, H302; Skin Sens. 1, H317
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<0.1%
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Muta. 2, H341; Carc. 2, H351; Additional information: For the wording of the listed risk phrases refer to section 16.
SECTION 4: First aid measures
4.1 Description of first aid measures
After inhalation: Supply fresh air; consult doctor in case of complaints.
After skin contact: Immediately wash with water and soap and rinse thoroughly.
After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing:
If symptoms persist consult doctor.
Call a doctor immediately.
4.2 Most important symptoms and effects, both acute and delayed Breathing difficulty
4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.
SECTION 5: Firefighting measures
5.1 Extinguishing media
Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
For safety reasons unsuitable extinguishing agents: Water with full jet
5.2 Special hazards arising from the substance or mixture Nitrogen oxides (NOx)
5.3 Advice for firefighters
Protective equipment: Wear self-contained respiratory protective device.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation
6.2 Environmental precautions: Do not allow product to reach sewage system or any water course.
6.3 Methods and material for containment and cleaning up:
Allow to solidify. Pick up mechanically.
Ensure adequate ventilation.
6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Store in cool, dry place in tightly closed receptacles.
Keep away from heat and direct sunlight.
Ensure good ventilation/exhaustion at the workplace.
Information about fire - and explosion protection: No special measures required
7.2 Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:
Store in a cool location.
Store only in the original receptacle.
Information about storage in one common storage facility: Store away from oxidising agents.
Further information about storage conditions: Keep container tightly sealed.
7.3 Specific end use(s) No further relevant information available.
SECTION 8: Exposure controls/personal protection
Additional information about design of technical facilities: No further data; see item 7.
8.1 Control parameters
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Ingredients with limit values that require monitoring at the workplace: |
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7085-85-0 ethyl 2-cyanoacrylate |
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WEL Short-term value: 1.5 mg/mÑ, 0.3 ppm |
Additional information: The lists valid during the making were used as basis.
8.2 Exposure controls
Personal protective equipment:
General protective and hygienic measures:
The usual precautionary measures are to be adhered to when handling chemicals.
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Avoid contact with the eyes and skin.
Respiratory protection:
Not necessary if room is well-ventilated.
Use suitable respiratory protective device in case of insufficient ventilation.
Protection of hands:
Protective gloves
Impervious gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves Nitrile rubber, NBR
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
Not suitable are gloves made of the following materials:
Rubber gloves
PVC gloves
Eye protection:
Safety glasses
Protective gloves
Body protection: Protective work clothing
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
General Information
Appearance:
Form: Liquid
Colour: Black
Odour: Characteristic
Odour threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: > 150 °C
Flash point: 87 °C
Flammability (solid, gaseous): Not applicable.
Ignition temperature:
Decomposition temperature: Not determined.
Self-igniting: Product is not self igniting.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: Not determined.
Upper: Not determined.
Vapour pressure at 20 °C: 0.27 hPa
Density at 20 °C: 1.05 g/cmÑ
Bulk density at 20 °C: 1.05 kg/mÑ
Relative density Not determined.
Vapour density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
water: Not miscible or difficult to mix.
Partition coefficient (n-octanol/water): Not determined.
Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
Solvent content:
Organic solvents: 0.0 %
VOC (EC) 0.00 %
9.2 Other information No further relevant information available.
SECTION 10: Stability and reactivity
10.1 Reactivity
10.2 Chemical stability
Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
10.3 Possibility of hazardous reactions
Exothermic polymerisation.
Reacts with alcohols.
Reacts with alcohols, amines, aqueous acids and alkalis.
Reacts with water and acids.
Reacts with amines.
Reacts with water.
Reacts with alkali (lyes).
10.4 Conditions to avoid No further relevant information available.
10.5 Incompatible materials: No further relevant information available.
10.6 Hazardous decomposition products: No dangerous decomposition products known.
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity:
Primary irritant effect:
on the skin: Irritant to skin and mucous membranes.
on the eye: Irritating effect.
Sensitisation: Sensitisation possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EU Classification Guidelines
for Preparations as issued in the latest version:
Irritant
SECTION 12: Ecological information
12.1 Toxicity
Aquatic toxicity: No further relevant information available.
12.2 Persistence and degradability No further relevant information available.
12.3 Bioaccumulative potential No further relevant information available.
12.4 Mobility in soil No further relevant information available.
Additional ecological information:
General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
12.5 Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
12.6 Other adverse effects No further relevant information available.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
Uncleaned packaging:
Recommendation: Disposal must be made according to official regulations.
SECTION 14: Transport information
14.1 UN-Number
ADR, ADN, IMDG, IATA Void
14.2 UN proper shipping name
ADR, ADN, IMDG, IATA Void
14.3 Transport hazard class(es)
ADR, ADN, IMDG, IATA
Class Void
14.4 Packing group
ADR, IMDG, IATA Void
14.5 Environmental hazards:
Marine pollutant: No
14.6 Special precautions for user Not applicable.
14.7 Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
UN "Model Regulation": -
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
No further relevant information available.
15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out
SECTION 16: Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific
product features and shall not establish a legally valid contractual relationship.
Relevant phrases
H302 Harmful if swallowed.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H341 Suspected of causing genetic defects.
H351 Suspected of causing cancer.
H400 Very toxic to aquatic life.
Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous
Goods by Road)
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
VOC: Volatile Organic Compounds (USA, EU)
Acute Tox. 4: Acute toxicity, Hazard Category 4
Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2
Eye Dam. 1: Serious eye damage/eye irritation, Hazard Category 1
Eye Irrit. 2: Serious eye damage/eye irritation, Hazard Category 2
Skin Sens. 1: Sensitisation - Skin, Hazard Category 1
Muta. 2: Germ cell mutagenicity, Hazard Category 2
Carc. 2: Carcinogenicity, Hazard Category 2
STOT SE 3: Specific target organ toxicity - Single exposure, Hazard Category 3
Aquatic Acute 1: Hazardous to the aquatic environment - AcuteHazard, Category 1
